The following temperature-composition data were obtained for a mixture of octane (0) and toluene (T) at 760 Torr, wherexis the mole fraction in the liquid and ythe mole fraction in the vapour at equilibrium .θ/°C 110.9 112.0 114.0 115.8 117.3 119.0 120.0 123.0Xr 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097YT0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164The boiling points are 110.6 °C for toluene and 125.6 °C for octane. Plot the temperatur-composition diagram of the mixture . What is the composition of the vapour in equilibrium with the liquid of composition (a)XT= 0.250 and (b)xO= 0.250?
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