The following table shows the acetone mols adsorbed on active carbon per gr of carbon, at a function of the concentrations, at 18 ºC. a) Which is the most adequate isotherm: Langmuir, Temkin or...


The following table shows the acetone mols adsorbed on active carbon per gr of carbon, at a function of the concentrations, at 18 ºC.
a) Which is the most adequate isotherm: Langmuir, Temkin or Freundlich? Justify
b) Calculate the magnitudes relevant for the chosen isotherm.
Since the adsorption is given in a liquid solution, c and s are, respectively, equivalent to pressure (p) and adsorbed volume (v).


Results: a) Freundlich isotherm is the most adequate: log s = -0.8751 + 0.5459 log c, R = 0.99978. (Langmuir R = 0.983; Temkin: R = 0.9745).

b) k = 0.139 mmol Acet./g C and a = 0.5459.



a function of the concentrations, at 18 °C.<br>c ( mmol/cm³)<br>84<br>165<br>390<br>800<br>s (mmol acet./g C)<br>1.50<br>2.15<br>3.50<br>5.10<br>a) Which is the most adequate isotherm: Langmuir, Temkin or Freundlich? Justify<br>b) Calculate the magnitudes relevant for the chosen isotherm.<br>Since the adsorption is given in a liquid solution, c and s are, respectively, equivalent to<br>pressure (p) and adsorbed volume (v).<br>Results: a) Freundlich isotherm is the most adequate: log s = -0.8751 + 0.5459 log c, R =<br>0.99978. (Langmuir R = 0.983; Temkin: R = 0.9745).<br>b) k = 0.139 mmol Acet./g C and a = 0.5459.<br>

Extracted text: a function of the concentrations, at 18 °C. c ( mmol/cm³) 84 165 390 800 s (mmol acet./g C) 1.50 2.15 3.50 5.10 a) Which is the most adequate isotherm: Langmuir, Temkin or Freundlich? Justify b) Calculate the magnitudes relevant for the chosen isotherm. Since the adsorption is given in a liquid solution, c and s are, respectively, equivalent to pressure (p) and adsorbed volume (v). Results: a) Freundlich isotherm is the most adequate: log s = -0.8751 + 0.5459 log c, R = 0.99978. (Langmuir R = 0.983; Temkin: R = 0.9745). b) k = 0.139 mmol Acet./g C and a = 0.5459.

Jun 10, 2022
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