The following data were obtained in the construction of a calibration plot for the determination of ruthenium (VI) using a polarographic method:
Ruthenium (VI) Concentration (μg/ml)
Limiting Current
(μA)
0
2
23.3
4
48.5
6
78.7
8
107.3
10
131.8
13
154.3
16
204.4
20
238.0
1.2702g of a dry solid sample containing an unknown amount of Ru6+was dissolved in aqueous solution and made up to the 250ml mark. 20.0ml of this solution were further diluted to 50ml. A current reading of 151.2μA was obtained for this latter solution. Using a linear graphical method, calculate the percent-by-weight (%w/w) of Ru6+in the unknown solid sample.
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