Sulfuryl chloride (SO 2 Cl 2 ) decomposes to sulfur dioxide (SO 2 ) and chlorine (Cl 2 ) by reaction in the gas phase. The following pressure data were obtained when a sample containing 5.00 x 10 -2...


Sulfuryl chloride (SO2Cl2) decomposes to sulfur dioxide (SO2) and chlorine (Cl2) by reaction in the gas phase. The following pressure data were obtained when a sample containing 5.00 x 10-2
mol sulfuryl chloride was heated to 600.K in a 5.00 x 10-1-L container.

























Time (hours):





0.00





1.00





2.00





4.00





8.00





16.00





Pso2cl2 (atm) :





4.93





4.26





3.52





2.53





1.30





0.34




Defining the rate as -∆SO2Cl2/∆t ,


a.determine the value of the rate constant for the decomposition of sulfuryl chloride at 600.K.


b.what is the half-life of the reaction?


c.what fraction of the sulfuryl chloride remains after 20.0 h?



Jun 07, 2022
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