In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H20) according to the reaction equation below. 4HCI + 02 - 2cl, + 2H20 An equal...

Extracted text: In Deacon process, gas phase reaction was carried out in isothermal batch reactor to form chlorine (Cl2) and water (H20) according to the reaction equation below. 4HCI + 02 - 2cl, + 2H20 An equal molar of HCI and O2 are fed to the reactor with total pressure of 4.7 atm and 300 °C as reaction temperature. By taking HCl as limiting reactant, the following experimental data were recorded from constant batch reactor volume: Table 1 Experimental data in an isothermal batch reactor t (min) P (atm) 50 100 150 250 1.04 0.916 0.817 200 300 2.35 1.78 1.44 1.20 Rate law of the above reaction respond to -TA=KCA°CBP, in which B is zero order with respect to oxygen. Given R as 0.082 atm. dm/mol. K. Construct a stoichiometric table and determine the reaction order and the rate constant using numerical method (differentiation).