At 500 K in the presence of a copper surface, ethanol decomposes according to the equation C 2 H 5 OH(g) →CH 3 CHO(g)+H 2 (g) The pressure of C 2 H 5 OH was measured as a function of time and the...


At 500 K in the presence of a copper surface, ethanol decomposes according to the equation


C2H5OH(g) →CH3CHO(g)+H2(g)


The pressure of C2H5OH was measured as a function of time and the following data were obtained:




































Time(s)






PC2H5OH (torr)





0





250.





100.





237





200.





224





300.





211





400.





198





500.





185




Since the pressure of a gas is directly proportional to the concentration of gas, we can express the rate law for a gaseous reaction in terms of partial pressures. Using the above data, deduce the rate law, the integrated rate law, and the value of the rate constant, all in terms of pressure units in atm and time in seconds. Predict the pressure of C2H5OH after 900. s from the start of the reaction. (Hint: To determine the order of the reaction with respect to C2H5OH, compare how the pressure of C2H5OHdecreases with each time listing.)



Jun 07, 2022
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