Ammonia, NH3, in air is being absorbed into water within the enclosed tank shown in the figure below. The liquid and gas phases are both well mixed, and mass transfer occurs only at the exposed gas–liquid interface. The diameter of the cylindrical tank is 4 m, total liquid volume inside the tank is
constant. The bulk gas pressure of ammonia is maintained at 0.02 atm, and the total gas pressure is constant at 1.0 atm. The system is isothermal at 20C. The inlet volumetric flow rate of water is 200 L/h and enters NH3free. You may assume that Henry’s law, pAi HcAidescribes the equilibrium distribution of NH3between the gas and the liquid phases where H 0.02 atm/(kg mol/m3). The film mass-transfer coefficients are kG 1:25 kg mol/m2h atm and kL 0:05 kg mol/m2h (kg mol/m3).
a. Determine the overall mass transfer coefficient, KG.
b. Determine the partial pressure of NH3 at the gas–liquid interface, pAi.
c. Determine WAthe total molar rate of ammonia transfer.
d. Develop a material balance for NH3; then determine cAithe concentration of NH3in the outlet liquid stream.
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