A 1.509-g sample of a Pb/Cd alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of the diluted solution was brought to a pH of 10.00 with a NH 4 + /NH...

A 1.509-g sample of a Pb/Cd alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of the diluted solution was brought to a pH of 10.00 with a NH₄
⁺/NH₃buffer; the subsequent titration involved both cations and required 28.89 mL of 0.06950 M EDTA. A second 50.00-mL aliquot was brought to a pH of 10.00 with an HCN/NaCN buffer, which also served to mask the Cd²⁺; 11.56 mL of the EDTA solution were needed to titrate the Pb²⁺. Calculate % Cd in the sample. Express your answer in 2 decimal places.




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