2. Consider a binary mixture of bromobenzene and chlorobenzene. Assume bromobenzene and chlorobenzene form an ideal mixture, and the vapor pressure for the pure compounds can be obtained from the...


2. Consider a binary mixture of bromobenzene and chlorobenzene. Assume bromobenzene and<br>chlorobenzene form an ideal mixture, and the vapor pressure for the pure compounds can be<br>obtained from the Antoine equation:<br>В<br>log 10<br>Psat<br>= A -<br>t+ C<br>where Psat is in torr (1 atm = 760 torr) and t is in °C. The Antoine constants for bromobenzene<br>and chlorobenzene are:<br>Component<br>Bromobenzene<br>Chlorobenzene<br>Applicable Range<br>47 to 177 °C<br>47 to 147 °C<br>A<br>B<br>6.86060<br>1438.820<br>205.540<br>6.97810<br>1431.050<br>217.650<br>а.<br>Estimate the boiling points at 1 atm for pure bromobenzene and pure chlorobenzene.<br>b. Calculate the bubble point (Tpubble) for a mixture of 40 mol % bromobenzene and 60 mol %<br>chlorobenzene.<br>c. Calculate the dew point (Tdew) for a mixture of 40 mol % bromobenzene and 60 mol %<br>chlorobenzene.<br>d. Calculate the liquid and vapor compositions for a mixture of 40 mol % bromobenzene and<br>60 mol % chlorobenzene at equilibrium with moles liquid (L) / moles vapor (V) = 3.<br>e. Recalculate the dew point (Tdew) for a mixture of 60 mol % bromobenzene and 40 mol %<br>chlorobenzene. Please compare the dew points of the mixtures in parts (c) and (e) - which<br>mixture yields a higher dew point and why?<br>

Extracted text: 2. Consider a binary mixture of bromobenzene and chlorobenzene. Assume bromobenzene and chlorobenzene form an ideal mixture, and the vapor pressure for the pure compounds can be obtained from the Antoine equation: В log 10 Psat = A - t+ C where Psat is in torr (1 atm = 760 torr) and t is in °C. The Antoine constants for bromobenzene and chlorobenzene are: Component Bromobenzene Chlorobenzene Applicable Range 47 to 177 °C 47 to 147 °C A B 6.86060 1438.820 205.540 6.97810 1431.050 217.650 а. Estimate the boiling points at 1 atm for pure bromobenzene and pure chlorobenzene. b. Calculate the bubble point (Tpubble) for a mixture of 40 mol % bromobenzene and 60 mol % chlorobenzene. c. Calculate the dew point (Tdew) for a mixture of 40 mol % bromobenzene and 60 mol % chlorobenzene. d. Calculate the liquid and vapor compositions for a mixture of 40 mol % bromobenzene and 60 mol % chlorobenzene at equilibrium with moles liquid (L) / moles vapor (V) = 3. e. Recalculate the dew point (Tdew) for a mixture of 60 mol % bromobenzene and 40 mol % chlorobenzene. Please compare the dew points of the mixtures in parts (c) and (e) - which mixture yields a higher dew point and why?

Jun 08, 2022
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